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Quantum Mechanics}Bohr Theory

It's amazing how far one can get with the Bohr formula.

To start with, one should calculate the ground-state energy of the singly ionized Helium (i.e., the ionization energy). E_1 = Z^2 E_{H1} = 4 \times 13.6 eV, since Helium has 2 protons. (The general formula is E_n = Z^2/n^2 E_1.)

The Bohr formula gives E=E_1\left(1/n_f^2-1/n_i^2\right)=E_1(1/n_f^2-1/16), since n_i^2=4^2=16.

E=hc/\lambda\approx 1.24E-6/4.7E-7 gives E\approx 2.5 eV.

The only unknown expression above is n_f. Plugging everything in and solving for that, n_f^{-2}\approx 8^{-1} \Rightarrow  n_f\approx 3. This yields choice (A). One can check via E_f=E_1/n_f^2 4\times 13.6/9 \approx 6, which verifies (A).

See below for user comments and alternate solutions! See below for user comments and alternate solutions!
Alternate Solutions
archard
2010-07-15 13:50:25
You can also get it with the Rydberg formula, since you're given the wavelength of the photon and the initial energy level. Then it's just plug and chug.Alternate Solution - Unverified
Comments
archard
2010-07-15 13:50:25
You can also get it with the Rydberg formula, since you're given the wavelength of the photon and the initial energy level. Then it's just plug and chug.Alternate Solution - Unverified
asdfman
2009-11-05 00:37:16
You can quickly narrow this down as anything less than ~400 nm is UV. If you remember that 13.6 eV, from hydrogen yields UV then that tosses out choices C, D, and E. NEC
f4hy
2009-10-25 19:28:33
I am confused. When finding E = \frac{hc}{\lambda} are you using the speed of light in cm but the wave length in meters?
kroner
2009-10-29 14:13:19
Everything is in meters there.
hc \approx 1.24E-6 eV m or 1240 eV nm,
which good value to know off-hand for problems like this.
NEC
astro_allison
2005-12-08 22:50:07
don't you mean E_{f} = \frac{Z^2 E_{0}}{n_{f}^2}?NEC

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