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\prob{51}
A particle of mass m is confined to an infinitely deep square-well potential:
<br />
 V(x)&=&\infty,\;\;x\leq0,x\geq a \\<br />
 V(x)&=&0,\;\;0\lt x \lt a<br />

The normalized eigenfunctions, labeled by the quantum number n, are $\psi_n=\sqrt{\frac{2}{a}}\sin \frac{n\pi x}{a}$

For any state n, the expectation value of the momentum of the particle is


  1. 0
  2. $\hbar n \pi/a$
  3. $\hbar n \pi/a$
  4. $2\hbar n \pi/a$
  5. $\hbar n \pi/a(\cos n\pi - 1)$
  6. $-i\hbar n \pi/a(\cos n\pi - 1)$

Quantum Mechanics}Momentum

The momentum operator in position space is given by p = \hbar/ i \frac{\partial}{\partial x}.

Thus, given the wave function, one can calculate the expectation value as \langle \psi_n | p | \psi_n \rangle = \langle \psi_n | \hbar/ i \frac{\partial | \psi_n \rangle}{\partial x}\propto \int_0^a \cos(n\pi x/a)\sin(n\pi x/a)dx =0, since sine's and cosine's are orthogonal over a whole period.

The answer is thus (A).

See below for user comments and alternate solutions! See below for user comments and alternate solutions!
Alternate Solutions
radicaltyro
2006-10-30 23:17:29
As Griffiths says, "As Peter Lorre would say, Do it ze kveek vay, Johnny!'". \langle p\rangle=m\frac{d\langle x\rangle}{dt} but \langle x\rangle=\frac{a}{2} for the infinite square well, so \langle p\rangle=0.Alternate Solution - Unverified
Comments
radicaltyro
2006-10-30 23:17:29
As Griffiths says, "As Peter Lorre would say, Do it ze kveek vay, Johnny!'". \langle p\rangle=m\frac{d\langle x\rangle}{dt} but \langle x\rangle=\frac{a}{2} for the infinite square well, so \langle p\rangle=0.Alternate Solution - Unverified
tera
2006-08-21 05:28:40
The expectation value of p is zero because otherwise the particle would tend either to go to the right or left and leave the well potential which is impossible!!!!!NEC
jcain6
2005-11-22 18:58:36
The expectation value of p must be real. When the integral is set up, complex number i can be factored out to the front of the integral. With i in front of the integral the only way for the expectation value of p to be real is for the integral to produce imaginary numbers or for the integral to equal zero. Since there is no hope that the integral will produce complex numbers in this case the expectation value of p must be zero. Just a way to save a little time!
a19grey2
2008-11-02 11:13:07
Yeah, this is the fastest way for me to do it. Also, it applies more generally and it says that the expectation of the momentum will be zero any time that the derviative with respect to x doesn't bring out any factors of i.
NEC

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